A method for manufacturing a hollow metal sphere with a mesoporous structure is disclosed, which comprises the following steps: (A) providing a hollow sphere template with a mesoporous structure, wherein the hollow sphere template comprises: a first shell with plural channels penetrating the first shell, the material of the first shell comprises a mesoporous silica material, and the mesoporous silica material has a cubic Ia3d symmetry pore structure; (B) mixing the hollow sphere template with a metal precursor; (C) reducing the metal precursor; and (D) removing the hollow sphere template to obtain a hollow metal sphere with a mesoporous structure. In addition, the present invention also provides a hollow metal sphere with a mesoporous structure prepared by the aforementioned method. |