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專利名稱(中) 增加共軛導電高分子β-phase含量之方法及其在高分子發光二極體上之應用
專利名稱(英) Method of Increasing β-Phase Content in a Conjugated Polymer Useful as a Light Emitting Layer in a Polymer Light Emitting Diode
專利家族 美國:8,287,941
專利權人 國立清華大學 100%
發明人 盧信宏,張智浩,劉景洋,陳壽安
技術領域 材料化工,光電光學
專利摘要(中)
A simple and efficient method for transforming conformation of parts of chains in the amorphous phase in a conjugated polymer to extended conjugation length (termed as .beta. phase) is disclosed. The .beta. phase acts as a dopant and can be termed self-dopant. The generated self-dopant in the amorphous host allows an efficient energy transfer and charge trapping to occur and leads to more balanced charge fluxes and more efficient charge recombination. For example, a polyfluorene film was dipped into a mixed solvent/non-solvent, tetrahydrofuran/methanol in volume ratio of 1:1, to generate a .beta.-phase content up to 1.32%. A polymer light emitting diode with the dipped polyfluorene film as a light emitting layer therein provides a more pure and stable blue-emission (solely from the self-dopant) with CIE color coordinates x+y<0.3 and a performance of 3.85 cd A.sup.-1 (external quantum efficiency 3.33%) and 34326 cd m.sup.-2.
專利摘要(英)
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聯絡資訊
承辦人姓名 周家鳳
承辦人電話 03-5715131 #34576
承辦人Email cf.chou@mx.nthu.edu.tw
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