The present disclosure provides a copolymerization method of vinyl acetate and styrene, which includes the following steps. A first mixing step is performed, wherein a first monomer, a reversible addition fragmentation chain transfer agent and a radical initiator are mixed to form a first mixture. A first heating step is performed, wherein the first mixture is heated to form a polymer. A second mixing step is performed, wherein a second monomer, the reversible addition fragmentation chain transfer agent and the radical initiator are added in the polymer to form a second mixture. A second heating step is performed, wherein the second mixture is heated to form a copolymer. The first monomer and the second monomer are different and are each independently vinyl acetate or styrene. Accordingly, the present disclosure can directly form a copolymer of vinyl acetate and styrene. |